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Catalytic conversion of furfural-acetone condensation products into bioderived C8 linear alcohols over Ni-Cu/Al-SBA-15
Catalysis Communications, Vol. 114, August 2018, Pages 42-45
- Category: Článek v odborném periodiku (Article in a professional journal)
- Author: Bertella Francine, Göpel Michael, Hidalgo Herrador José Miguel, Kikhtyanin Oleg, Kubička David, Martínez Austín, Ramos Rubén, Tišler Zdeněk
- ISSN: 1566-7367
- Year: 2018
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Link:
URL
- DOI: 10.1016/j.catcom.2018.06.006
Review
The production of C8 linear diols from a furfural-acetone condensation product has been achieved for the first time using a non-noble metal based catalyst. In particular, SBA-15 supported NieCu bimetallic catalyst showed the best hydrogenating activity reaching an outstanding yield (ca. 63%) of the fully saturated product. The incorporation of acidity by the preparation of NieCu/Al-SBA-15 resulted in the promotion of ring-opening steps, which led to a remarkable yield of C8 linear diols (28%). These results establish a competitive catalytic route for the production of bio-based diols over cost-efficient 3d transition metal-based catalysts.