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A process of transforming hydrotalcite, containing Cu - Zn – Al (2:1:1) to a catalysts for selective hydrogenolysis of glycerol to 1,2-propanediol has been studied. A two steps process, consisted of the calcination at increased temperature and subsequent reduction with hydrogen, as well as a one step process, in which the hydrotalcite was heated at hydrogen atmosphere so the calcination and reduction were joined to one operation, were verified experimentally. The influence of the temperature in the calcination step in the two steps process on composition, texture and catalytic properties of the active form of catalyst has been studied in detail. X Ray diffraction, thermogravimetric analyses, nitrogen physisorption, mercury porosimetry, temperature-programmed reduction and high-resolution transmission electron microscopy were used for the catalysts characterization.