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Impact of dopant metal ions in the framework of parent zirconia on the n-heptane isomerization activity of the Pt/WO3-ZrO2 catalysts
Journal of Molecular Catalysis A: Chemical, Volume 420, 1 August 2016, Pages 107 - 114
- Category: Článek v odborném periodiku (Article in a professional journal)
- Author: Bortnovskiy Oleg, Černý Radek, Hidalgo Herrador José Miguel, Kaucký Dalibor, Sobalík Zdeněk
- ISSN: 1381-1169
- Year: 2016
- Link: URL
- DOI: 10.1016/j.molcata.2016.04.015
Review
Selected Pt/WO3-ZrO2 catalysts, promoted by Al, Si and Fe metal ions and isomorphously substituted into the zirconia framework, were studied and compared with their undoped equivalents as catalysts for C7 isomerization. They were characterized by XRD, UV–vis and TPD-TPR techniques. A mechanism wasproposed for the positive dopant effect on the catalyst activity.