Publication Search
Gas chromatic data and identification of isomeric products of cyycloaddition reactions of conjugated C5 dienes
Petroleum & Coal; Vol 54; Issue 4; 2012; Pages 385-396
- Category: Článek v odborném periodiku (Article in a professional journal)
- Author: Kolena Jiří, Krupka J.
- ISSN: 1337-7027
- Year: 2012
Review
Dimers and codimers resulting from thermal cycloaddition reactions of 1,3-cyclopentadiene, isoprene, cis-1,3-pentadiene and trans-1,3-pentadiene were characterised in terms of their Kovats retention indices on a HP-PONA capillary column at 100°C. The proportion of individual isomers in dimerisation andcodimerisation products under defined reaction conditions and their chromatographic characteristics were compared with published data. The chemical structure of isomer products was assigned on the basis of agreement between experimental and literature data.