Hledat publikace
Conversion of Vegetable Oils into Hydrocarbons over CoMo/MCM-41 Catalysts
Topics in Catalysis; Vol 53; Issue 3; 2010; Pages 168-178
- Druh výsledku: Článek v odborném periodiku (Article in a professional journal)
- Autor: Bejblová Martina, Kubička David, Vlk Josef
- ISSN: 1022-5528
- Vydáno/uděleno: 2010
- Link: URL
- DOI: 10.1007/s11244-009-9421-z
Popis
The catalysts were tested in a flow reactor at reaction temperatures 300 and 320 _C, hydrogen pressures 2–11 MPa and space velocities 1–4 h-1 using refined rapeseed oil as a feedstock. Incorporation of Al into the framework of MCM-41 led to an increase of both conversion of triglycerides and selectivity to hydrocarbons, namely n-heptadecane and n-octadecane. However, the conversion of triglycerides was lower than that achieved over alumina supported CoMo. Moreover, the rather high selectivity to oxygenated products, as compared with alumina supports, has made possible a detailed description of the reaction intermediates and their dependence on the reaction conditions.